After deployment of SRM 8.3 vAPP, you can select Site Recovery from with the vCenter Client

Click on NEW SITE PAIR

Select your primary site vCenter as the 1^st Site

In the Second Site details, enter the PSC (or vCenter) Address for 2^nd site with admin priviledges (As this is a lab I’ve used the default admin account, here you could have a service account.

This will pull in the vCenter (if separate PSC) you have entered above..

Select Site Recovery Manager as the service.

You may get a couple of security alerts and have to accept some security certs. Once complete click Finish on the Summary Page.

You have successfully paired 2 sites in SRM!